Summary
Question: I know that mystic topaz and aqua aura quartz are created using an electrodeposition sputtering process. Gold or other metals are “sputtered” as a coating on gemstones. My question is: how? Can someone please explain how vapor deposition works?
Reading time: 2 min
mystic topaz pendant

“Tulip (1),” 14k white gold pendant with mystic topaz. Photo by Mark Somma. Licensed under CC By 2.0.

How Vapor Deposition Creates A Metal Coating

I once built and operated a machine for vapor deposition. Imagine a glass bell jar connected to very powerful vacuum pumps. I had a good mechanical pump that created a vacuum of less than one millimeter of mercury pressure. But that’s only useful for sputtering. Evaporation requires a fairly high-voltage arc and electrodes composed of the metal that you want to deposit on a gemstone or other surface. Sputtering doesn’t give quite as good a result as evaporation.

vapor deposition chamber

A chemical vapor deposition chamber in action. Photo by Polyparadigm. Public Domain.

At that pressure, I activated a pair of large rings at a voltage of 10,000v AC. This bombarded the job (in my case, 3-inch concave glass lenses) with atoms of very active oxygen, which cleaned up any microscopic traces of organic material remaining after a very thorough initial cleaning.

During this bombardment process, the entire bell jar glowed with a pale violet-pink light. After a few seconds, I switched this off, and the oil diffusion pump started up. This pump had no moving parts but could pull a vacuum of 0.00001 mm of mercury pressure, but only if the mechanical “backing pump” had removed the majority of the air first.

Next, I applied a low-voltage, high-amperage current (about 50 amps at 3 volts) to a heavy tungsten coil. The coil became white hot. Bits of gold, copper, and aluminum (or other metals which had been clipped on to it) began to boil and evaporated. Since there was very little atmosphere in the jar at this stage, the metal atoms got sufficient energy to travel in straight lines without colliding with air molecules anywhere in the jar. These metal atoms then coated the jar and anything inside it.

Sometimes, instead of using a tungsten coil, a little boat-shaped dish is used to contain the metal to be evaporated. Pure silica is often used, too. The vapor deposition process is completely controllable. You can create a coat of any thickness up to a micron or two. You can create an iridescent effect over rocks, glass, cabochons, or other cut gemstones.

John Burgess

Aqua aura quartz crystal - chemical vapor deposition

A vapor deposition process creates aqua aura quartz, like this crystal, by coating a quartz piece with gold. Photo by mangovall. Licensed under CC By-ND 2.0.

More Applications of?Vapor Deposition

Vapor deposition, also called vacuum deposition, is a widely used process. In electron microscopy, viewing samples receive gold coatings this way, since the electron microscope can only accurately image a conductive surface. Plastics can also be “metalized.” Some plastic toy models have chromed parts made in this manner.

It’s possible to hook up multiple electrodes or coils simultaneously in the vapor deposition process. Since they don’t have to be the same materials, you can deposit layers of a metal mixture that might be quite hard to produce by other means.

Peter Rowe

Mystic Topaz

Mystic topaz. Photo by Sandy Roberts. Licensed under CC By 2.0.